Painter XI/Wacom tablet (one layer painting).
References used.
Drawn from scratch and observation.
The tutorial:

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Note:
Watermark added.
Please don't use my art for commercial purposes thank you.

Loki again~
Yes this is a drawing (and a really long time-consuming one too
especially that face @___@). Ill be uploading a step-by-step very soon on how I drew this from start to finish.
This was good practice to use a bit more of the grey palette than the usual strong saturation work that I'm used to.
Other Marvel/Loki art:




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Gives a nice shot of the full body.